Chloromethane to olefins over H-SAPO-34: Probing the hydrocarbon pool mechanism
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چکیده
منابع مشابه
Ultra-short contact time conversion of chloromethane to olefins over pre-coked SAPO-34: direct insight into the primary conversion with coke deposition.
Hydrocarbon species trapped in the catalyst that work as the reaction center and govern the conversion and product selectivity of chloromethane transformation were revealed by a very efficient home-made ultra-short contact time pulse reaction system over pre-coked SAPO-34.
متن کاملEffect of Feedstock and Catalyst Impurities on the Methanol‐to‐Olefin Reaction over H‐SAPO‐34
Operando UV/Vis spectroscopy with on-line mass spectrometry was used to study the effect of different types of impurities on the hydrocarbon pool species and the activity of H-SAPO-34 as a methanol-to-olefins (MTO) catalyst. Successive reaction cycles with different purity feedstocks were studied, with an intermittent regeneration step. The combined study of two distinct impurity types (i.e., f...
متن کاملInfluence of the Reaction Temperature on the Nature of the Active and Deactivating Species During Methanol-to-Olefins Conversion over H-SAPO-34
The selectivity toward lower olefins during the methanol-to-olefins conversion over H-SAPO-34 at reaction temperatures between 573 and 773 K has been studied with a combination of operando UV-vis diffuse reflectance spectroscopy and online gas chromatography. It was found that the selectivity toward propylene increases in the temperature range of 573-623 K, while it decreases in the temperature...
متن کاملOptimizing the crystallinity and acidity of H-SAPO-34 by fluoride for synthesizing Cu/SAPO-34 NH3-SCR catalyst.
A series of H-SAPO-34 zeolites were synthesized by a hydrothermal method in fluoride media. The as-synthesized H-SAPO-34 zeolites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), N2 physisorption, temperature-programmed desorption of NH3 (NH3-TPD) and nuclear magnetic resonance (NMR) measurements. The results showed that a certain concentration of F(-) anions p...
متن کاملMethanol-to-Hydrocarbons Product Distribution over SAPO-34 and ZSM-5 Catalysts: The applicability of Thermodynamic Equilibrium and Anderson-Schulz-Flory Distribution
The product distribution of methanol to hydrocarbons conversion over SAPO-34 and ZSM-5 catalysts was studied using thermodynamic equilibrium and Anderson-Schulz-Flory (ASF) distributions. The equilibrium compositions were calculated using constrained Gibbs free energy minimization. The effect of catalyst type was considered by setting upper limits to product carbon number due to sh...
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ژورنال
عنوان ژورنال: Applied Catalysis A: General
سال: 2016
ISSN: 0926-860X
DOI: 10.1016/j.apcata.2016.09.004